[μ-10,22-Dichloro-3,6-bis(2-furylmethyl)-3,6,14,18-tetraazatricyclo[18.3.1.18,12]pentacosa-1(23),8,10,12(25),13,18,20(24),21-octaene-24,25-diolato-κ8 N 3,N 6,O 24,O 25:N 14,N 18,O 24:O 25]bis[chloridocopper(II)] acetonitrile solvate
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چکیده
The title compound, [Cu(2)(C(31)H(30)Cl(2)N(4)O(4))Cl(2)]·CH(3)CN, was synthesized by cyclo-condensation between N,N'-bis-(2-fur-yl)-N,N'-bis-(3-formyl-5-chloro-salicylaldehyde)ethyl-enediamine and 1,3-diamino-propane in the presence of Cu(II) ions. It is an unsymmetrical dinuclear Cu(II) complex. The coordination geometry for each Cu(II) atom can be discribed as distorted square-pyramidal. The two Cu atoms are bridged by two phenolate O atoms with a Cu⋯Cu distance of 3.0274 (9) Å.
منابع مشابه
[μ-(4S,5S,15S,16S)-10,21-Di-tert-butyl-4,5,15,16-tetraphenyl-3,6,14,17-tetraazatricyclo[17.3.1.18,12]tetracosa-1(23),8,10,12(24),19,21-hexaene-23,24-diolato-κ8 N 3,N 6,O 23,O 24:N 14 N 17,O 23,O 24]bis[(acetato-κO)zinc(II)] ethanol disolvate
In the title compound, [Zn(2)(C(36)H(42)N(4)O(2))(CH(3)COO)(2)]·2CH(3)CH(2)OH, a centrosymmetric dinuclear zinc macrocyclic complex is accompanied by two half-occupied ethanol solvent molecues resulting in a 1:2 macrocycle-solvent composition. The Zn(II) atom has a square-pyramidal geometry arising from an N(2)O(3) donor set, being coordinated by two N atoms and two O atoms from the macrocyclic...
متن کامل[μ-10,21-Dimethyl-3,6,14,17-tetraazatricyclo[17.3.1.18,12]tetracosa-1(23),8(24),9,11,19,21-hexaene-23,24-diolato-κ8 N 3,N 6,O 23,O 24:N 14,N 17,O 23,O 24]bis[(nitrato-κ2 O,O′)nickel(II)]
In the title centrosymmetric dinuclear nickel complex, [Ni(2)(C(22)H(30)N(4)O(2))(NO(3))(2)], each of the two Ni(II) atoms has a distorted octa-hedral geometry, defined by two N atoms and two O atoms from the macrocyclic ligand and two O atoms from a chelating nitrate anion. The two Ni atoms are bridged by two phenolate O atoms, forming a four-membered Ni(2)O(2) ring.
متن کامل[μ-10,21-Dimethyl-3,6,14,17-tetrazatricyclo[17.3.1.18,12]tetracosa-1(23),2,6,8,10,12 (24),13,17,19,21-decaene-23,24-diolato-κ4 N 3,N 6,O 23,O 24:κ4 N 14,N 17,O 23,O 24]bis(perchlorato-κO)dimanganese(II)
In the centrosymmetric and dinuclear title complex, [Mn(2)(C(22)H(22)N(4)O(2))(ClO(4))(2)], the two Mn atoms are bridged by two phenolate O atoms of the N(4)O(2) macrocycle with an Mn⋯Mn distance of 2.9228 (11) Å. The distorted square-pyramidal N(2)O(3) coordination geometry is completed by an O atom derived from a perchlorate anion.
متن کاملDiaqua[μ-11,23-di-tert-butyl-3,7,15,19-tetraazatricyclo[19.3.1.19,13]tetracosa-1(25),2,6,9,11,13(26),14,19,21,23-dodecaene-25,26-diolato-κ4 N 3,N 7,O 25,O 26:κ4 N 15,N 19,O 25,O 26]dicopper(II) bis(perchlorate)
In the dinuclear title complex, [Cu(2)(C(30)H(38)N(4)O(2))(H(2)O)(2)](ClO(4))(2), the coordination cation has crystallographically imposed twofold rotational symmetry. The Cu(II) ion is five-coordinated by two N and two O atoms from the macrocylic ligand and one O atom from a water mol-ecule, forming a square-pyramidal N(2)O(3) geometry with the water mol-ecule in the apical position. The dista...
متن کاملDi-μ2-methoxo-bis{[μ-3,10,18,25-tetraazapentacyclo[17.4.4.3.1.1]triconta-1(31),2,4(9),5,7,10,12,14,16(32),17,19(24),20,22,25,27,29-hexadecaene-31,32-diolato]dizinc(II)} bis(perchlorate) N,N-dimethylformamide disolvate
The title compound, [Zn(4)(C(28)H(18)N(4)O(2))(2)(CH(3)O)(2)](ClO(4))(2)·2C(3)H(7)NO, is a C2 symmetric tetra-nuclear zinc(II) complex comprised of two [Zn(2)L](2+) units bridged by a pair of μ(2)-OMe ligands (where L is the doubly-deprotonated form of the macrocyclic dinucleating ligand derived from the [2 + 2] Schiff base condensation between 2-hy-droxy-benzene-1,3-dicarbaldehyde and 1,2-diam...
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